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如何计算Polymer M W

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Polymer molecular weight affects properties: higher MW = stronger, higher Tg, lower solubility; calculated from monomers and chain length.

公式

Calculate M_w = n × M_monomer - (n-1) × 18 (water loss)

分步指南

  1. 1Input monomer molar mass and degree of polymerization (n)
  2. 2Calculate M_w = n × M_monomer - (n-1) × 18 (water loss)
  3. 3Show distribution effects

例题解析

输入
Polyethylene: C₂H₄ unit, n=1000
结果
M_w ≈ 28,000 g/mol (number average MW)

常见错误注意事项

  • Forgetting water loss in condensation polymerization
  • Confusing number-average vs. weight-average MW

常见问题

Why is molecular weight distribution important?

Broad distribution: poor flow processing, brittle; narrow: processable, stronger.

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